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Applicability of the Arrhenius model for Ammonia Oxidizing Bacteria subjected to temperature time gradients

Alberto MANNUCCI,Giulio MUNZ,Gualtiero MORI,Claudio LUBELLO,Jan A. OLESZKIEWICZ

《环境科学与工程前沿（英文）》 2015年 第9卷 第6期   页码 988-994 doi: 10.1007/s11783-014-0751-0

摘要： The aim of this work is to identify the range of applicability of Arrhenius type temperature dependence for Ammonia Oxidizing Bacteria (AOB) subjected to temperature time gradients through continuous titrimetric tests. An innovative online differential titrimetric technique was used to continuously monitor the maximum biologic ammonia oxidation rate of the biomass selected in a pilot scale membrane bioreactor, as a function of temperature time gradients. The monitoring technique is based on the measurement of alkalinity and hydrogen peroxide consumption rates in two parallel reactors operated in non-limiting substrate conditions for AOB; both reactors were continuously fed with mixed liquor and in one of them AOB were inhibited with allylthiourea. The effects of temperature decrease rates in the range 1 to 4°C·h were evaluated by controlling the titrimetric reactor in the temperature range 10°C–20°C. The dependence of growth kinetics on temperature time gradients and the range of applicability of Arrhenius model for temperature dependency of AOB growth kinetics were assessed. The Arrhenius model was found to be accurate only with temperature gradients lower than 2°C·h . The estimated Arrhenius coefficients ( ) were shown to increase from 1.07 to 1.6 when the temperature decrease rate reached 4°C·h .

关键词： nitrification rate     temperature effect     continuous titrimetric tests     time-gradient temperature variations     Ammonia Oxidizing Bacteria (AOB)    

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Phase separation time/temperature dependence of thermoplastics-modified thermosetting systems

ZHANG Xiujuan, XU Yuanze, YI Xiaosu

《化学科学与工程前沿（英文）》 2008年 第2卷 第3期   页码 276-285 doi: 10.1007/s11705-008-0057-5

摘要： The cure-induced phase separation processes of various thermoplastics(TP)-modified thermosetting systems which show upper critical solution temperature (UCST) or lower critical solution temperature (LCST) were studied with emphasis on the temperature dependency of the phase separation time and its potential application in the cure time-temperature processing window. We found that the phase separation time/temperature relationship follows the simple Arrhenius equation. The cure-induced phase separation activation energy (ps) generated from the linear fitting of the Arrhenius equation is irrelevant to the detection means of phase separation time. We also found that (ps) is insensitive to TP content, TP molecular weight and curing rate, but it changes with the cure reaction kinetics and the chemical environment of the systems. With the established phase separation time-temperature dependence relation, we can easily establish the whole cure time-temperature transformation (TTT) diagram with morphology information which is a useful map for the TP/TS composites processing industry.

关键词： separation time-temperature     temperature dependency     cure-induced     separation activation     temperature    

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Field test on temperature field and thermal stress for prestressed concrete box-girder bridge

Baoguo CHEN, Rui DING, Junjie ZHENG, Shibiao ZHANG

《结构与土木工程前沿（英文）》 2009年 第3卷 第2期   页码 158-164 doi: 10.1007/s11709-009-0002-9

摘要： A field test was conducted to investigate the distribution of temperature field and the variation of thermal stress for a prestressed concrete (PC) box-girder bridge. The change of hydration heat temperature consists of four periods: temperature rising period, constant temperature period, rapid temperature fall period and slow temperature fall period. The peak value of hydration heat temperature increases with the increasing casting temperature of concrete; the relation between them is approximately linear. According to field tests, the thermal stress incurred by hydration heat may induce temperature cracks on the PC box-girder. Furthermore, the nonlinear distribution of temperature gradient and the fluctuation of thermal stress induced by exposure to sunlight were also obtained based on continuous in-situ monitoring. Such results show that the prevailing Chinese Code (2004) is insufficient since it does not take into account the temperature gradient of the bottom slab. Finally, some preventive measures against temperature cracks were proposed based on related studies. The conclusions can provide valuable reference for the design and construction of PC box-girder bridges.

关键词： box-girder bridge     field test     hydration heat     temperature field     temperature gradient     thermal stress    

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Real-time tool condition monitoring method based on temperature measurement and artificial neural network

《机械工程前沿（英文）》 doi: 10.1007/s11465-021-0661-3

摘要： Tool failures in machining processes often cause severe damages of workpieces and lead to large quantities of loss, making tool condition monitoring an important, urgent issue. However, problems such as practicability still remain in actual machining. Here, a real-time tool condition monitoring method integrated in an in situ fiber optic temperature measuring apparatus is proposed. A thermal simulation is conducted to investigate how the fluctuating cutting heats affect the measuring temperatures, and an intermittent cutting experiment is carried out, verifying that the apparatus can capture the rapid but slight temperature undulations. Fourier transform is carried out. The spectrum features are then selected and input into the artificial neural network for classification, and a caution is given if the tool is worn. A learning rate adaption algorithm is introduced, greatly reducing the dependence on initial parameters, making training convenient and flexible. The accuracy stays 90% and higher in variable argument processes. Furthermore, an application program with a graphical user interface is constructed to present real-time results, confirming the practicality.

关键词： tool condition monitoring     cutting temperature     neural network     learning rate adaption    

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Development of realistic design fire time-temperature curves for the testing of cold-formed steel wall

Anthony Deloge ARIYANAYAGAM,Mahen MAHENDRAN

《结构与土木工程前沿（英文）》 2014年 第8卷 第4期   页码 427-447 doi: 10.1007/s11709-014-0279-1

摘要： Fire resistance rating of light gauge steel frame (LSF) wall systems is obtained from fire tests based on the standard fire time-temperature curve. However, fire severity has increased in modern buildings due to higher fuel loads as a result of modern furniture and light weight constructions that make use of thermoplastics materials, synthetic foams and fabrics. Some of these materials are high in calorific values and increase both the spread of fire growth and heat release rate, thus increasing the fire severity beyond that of the standard fire curve. Further, the standard fire curve does not include a decay phase that is present in natural fires. Despite the increasing usage of LSF walls, their behavior in real building fires is not fully understood. This paper presents the details of a research study aimed at developing realistic design fire curves for use in the fire tests of LSF walls. It includes a review of the characteristics of building fires, previously developed fire time-temperature curves, computer models and available parametric equations. The paper highlights that real building fire time-temperature curves depend on the fuel load representing the combustible building contents, ventilation openings and thermal properties of wall lining materials, and provides suitable values of many required parameters including fuel loads in residential buildings. Finally, realistic design fire time-temperature curves simulating the fire conditions in modern residential buildings are proposed for the testing of LSF walls.

关键词： fire safety     standard fire curve     realistic design fire time-temperature curves     light gauge steel frame (LSF) walls     fire resistance rating     fuel load    

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Evaluating the short-term effect of ambient temperature on non-fatal outdoor falls and road traffic injuriesamong children and adolescents in China: a time-stratified case-crossover study

《环境科学与工程前沿（英文）》 2023年 第17卷 第9期 doi: 10.1007/s11783-023-1705-1

摘要：

● A study assessing the temperature-injury relationship was conducted among students.

关键词： Ambient temperature     Fall     Road traffic injury     Student     China    

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New technique of precision necking for long tubes with variable wall thickness

Yongqiang GUO, Chunguo XU, Jingtao HAN, Zhengyu WANG

《机械工程前沿（英文）》 2020年 第15卷 第4期   页码 622-630 doi: 10.1007/s11465-019-0565-7

摘要： This study analyzed the deformation law of rear axles with variable wall thickness under bidirectional horizontal extrusion and found that necking was accompanied by upsetting deformation through theoretical calculation, numerical simulation, and experimental research. The sequence and occurrence of necking and upsetting deformations were obtained. A theory of deformation was proposed by controlling the distribution of temperature field. Effective processes to control the wall thickness of rear axle at different positions were also proposed. The ultimate limit deformation with a necking coefficient of 0.68 could be achieved using the temperature gradient coefficient. A new technology of two-step heating and two-step extrusion for a 13 t rear axle was developed, qualified test samples were obtained, and suggestions for further industrial application were put forward.

关键词： extrusion     rear axle     necking coefficient     temperature gradient    

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Supercritical carbon dioxide extraction of CLA-ethyl ester

Yingdi CHEN, Peng XU, Jian CHENG

《化学科学与工程前沿（英文）》 2011年 第5卷 第1期   页码 102-106 doi: 10.1007/s11705-010-0536-3

摘要： Supercritical carbon dioxide (SC-CO ) extraction of Conjugated linoleic acid (CLA) ethyl ester was investigated at pressures in the range of 9 to 10.5 MPa and temperature gradients ranging from 0°C to 21°C. The content of CLA-ethyl ester in the fraction was analyzed with gas chromatography (GC). The experimental results indicated that the rate of extraction would rise with the increase of pressure when temperature gradient was given. Moreover, the extraction pressure had insignificant influence on the selectivity of CLA-ethyl ester in SC-CO . When pressure was fixed, setting certain temperature gradient can improve the selectivity of CLA-ethyl ester in SC-CO , and CLA-ethyl ester can be concentrated more effectively than without a temperature gradient. The acid value and peroxide value of the fractions were reduced obviously, compared to the raw material. The optimal condition is pressure at 10 MPa and temperature gradient at 11°C.

关键词： supercritical carbon dioxide     extraction     CLA-ethyl ester     temperature gradient    

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Achieving High Strength and Tensile Ductility in Pure Nickel by Cryorolling with Subsequent Low-TemperatureShort-Time Annealing

Zhide Li,Hao Gu,Kaiguang Luo,Charlie Kong,Hailiang Yu,

《工程（英文）》 doi: 10.1016/j.eng.2023.01.019

摘要： ty. In this study, cryorolling under different strains followed by low-temperature short-time annealing was used to fabricate pure nickel sheets combining high strength with good ductility. The results show that, for different cryorolling strains, the uniform elongation was greatly increased without sacrificing the strength after annealing. A yield strength of 607 MPa and a uniform elongation of 11.7% were obtained after annealing at a small cryorolling strain (ε = 0.22), while annealing at a large cryorolling strain (ε = 1.6) resulted in a yield strength of 990 MPa and a uniform elongation of 6.4%. X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and electron backscattered diffraction (EBSD) were used to characterize the microstructure of the specimens and showed that the high strength could be attributed to strain hardening during cryorolling, with an additional contribution from grain refinement and the formation of dislocation walls. The high ductility could be attributed to annealing twins and micro-shear bands during stretching, which improved the strain hardening capacity. The results show that the synergistic effect of strength and ductility can be regulated through low-temperature short-time annealing with different cryorolling strains, which provides a new reference for the design of future thermo-mechanical processes.

关键词： Cryorolling     Annealing     Nickel     Strain hardening     Ductility    

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Effects of sulfur on variations in the chemical speciation of heavy metals from fly ash glass

《环境科学与工程前沿（英文）》 2023年 第17卷 第10期 doi: 10.1007/s11783-023-1728-7

摘要：

● A higher sulfur content reduced the curing rate of Cr in glass.

关键词： Dechlorinated fly ash     SO3     Heavy metal     Chemical speciation     Glass solidification    

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Genomic variations in the counterpart normal controls of lung squamous cell carcinomas

null

《医学前沿（英文）》 2018年 第12卷 第3期   页码 280-288 doi: 10.1007/s11684-017-0580-1

摘要：

Lung squamous cell carcinoma (LUSC) causes approximately 400 000 deaths each year worldwide. The occurrence of LUSC is attributed to exposure to cigarette smoke, which induces the development of numerous genomic abnormalities. However, few studies have investigated the genomic variations that occur only in normal tissues that have been similarly exposed to tobacco smoke as tumor tissues. In this study, we sequenced the whole genomes of three normal lung tissue samples and their paired adjacent squamous cell carcinomas. We then called genomic variations specific to the normal lung tissues through filtering the genomic sequence of the normal lung tissues against that of the paired tumors, the reference human genome, the dbSNP138 common germline variants, and the variations derived from sequencing artifacts. To expand these observations, the whole exome sequences of 478 counterpart normal controls (CNCs) and paired LUSCs of The Cancer Genome Atlas (TCGA) dataset were analyzed. Sixteen genomic variations were called in the three normal lung tissues. These variations were confirmed by Sanger capillary sequencing. A mean of 0.5661 exonic variations/Mb and 7.7887 altered genes per sample were identified in the CNC genome sequences of TCGA. In these CNCs, C:G→T:A transitions, which are the genomic signatures of tobacco carcinogen N-methyl-N-nitro-N-nitrosoguanidine, were the predominant nucleotide changes. Twenty five genes in CNCs had a variation rate that exceeded 2%, including ARSD (18.62%), MUC4 (8.79%), and RBMX (7.11%). CNC variations in CTAGE5 and USP17L7 were associated with the poor prognosis of patients with LUSC. Our results uncovered previously unreported genomic variations in CNCs, rather than LUSCs, that may be involved in the development of LUSC.

关键词： lung cancer     counterpart normal control     genomic variations    

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prediction and optimization design of sustainable concrete based on squirrel search algorithm-extreme gradient

《结构与土木工程前沿（英文）》   页码 1310-1325 doi: 10.1007/s11709-023-0997-3

摘要： Concrete is the most commonly used construction material. However, its production leads to high carbon dioxide (CO2) emissions and energy consumption. Therefore, developing waste-substitutable concrete components is necessary. Improving the sustainability and greenness of concrete is the focus of this research. In this regard, 899 data points were collected from existing studies where cement, slag, fly ash, superplasticizer, coarse aggregate, and fine aggregate were considered potential influential factors. The complex relationship between influential factors and concrete compressive strength makes the prediction and estimation of compressive strength difficult. Instead of the traditional compressive strength test, this study combines five novel metaheuristic algorithms with extreme gradient boosting (XGB) to predict the compressive strength of green concrete based on fly ash and blast furnace slag. The intelligent prediction models were assessed using the root mean square error (RMSE), coefficient of determination (R2), mean absolute error (MAE), and variance accounted for (VAF). The results indicated that the squirrel search algorithm-extreme gradient boosting (SSA-XGB) yielded the best overall prediction performance with R2 values of 0.9930 and 0.9576, VAF values of 99.30 and 95.79, MAE values of 0.52 and 2.50, RMSE of 1.34 and 3.31 for the training and testing sets, respectively. The remaining five prediction methods yield promising results. Therefore, the developed hybrid XGB model can be introduced as an accurate and fast technique for the performance prediction of green concrete. Finally, the developed SSA-XGB considered the effects of all the input factors on the compressive strength. The ability of the model to predict the performance of concrete with unknown proportions can play a significant role in accelerating the development and application of sustainable concrete and furthering a sustainable economy.

关键词： sustainable concrete     fly ash     slay     extreme gradient boosting technique     squirrel search algorithm     parametric analysis    

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Time- and temperature-dependence of compressive and tensile behaviors of polypropylene fiber-reinforced

《结构与土木工程前沿（英文）》 2021年 第15卷 第4期   页码 1025-1037 doi: 10.1007/s11709-021-0741-9

摘要： The understanding of compressive and tensile behaviors of polypropylene fiber-reinforced cemented paste backfill (FR-CPB) play crucial roles in the successful implementation of reinforcement technique in underground mine backfilling operations. However, very limited studies have been performed to gain insight into the evolution of compressive and tensile behaviors and associated mechanical properties of FR-CPB under various curing temperatures from early to advanced ages. Thus, this study aims to investigate the time (7, 28, and 90 d)- and temperature (20°C, 35°C, and 45°C)-dependence of constitutive behavior and mechanical properties of FR-CPB. The obtained results show that pre- and post-failure behaviors of FR-CPB demonstrate strongly curing temperature-dependence from early to advanced ages. Moreover, the pseudo-hardening behavior is sensitive to curing temperature, especially at early ages. Furthermore, the mechanical properties including elastic modulus, material stiffness, strengths, brittleness, cohesion, and internal friction angle of FR-CPB show increasing trends with curing temperature as curing time elapses. Additionally, a predictive model is developed to capture the strong correlation between compressive and tensile strength of FR-CPB. The findings of this study will contribute to the successful implementation of FR-CPB technology.

关键词： cemented paste backfill     fiber reinforcement     constitutive behavior     temperature     tailings    

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Seasonal and treatment-process variations in invertebrates in drinking water treatment plants

Zhiling Wu, Xianchun Tang, Hongbin Chen

《环境科学与工程前沿（英文）》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1354-6

摘要： Abstract • Seasonal and treatment-process variations in invertebrates in a DWTP were analyzed. • The propagation and leakage of invertebrates in BAC filter were the most serious. • Invertebrates can survive and reproduce in chlorine disinfected clear water tanks. • Proportions of endogenous invertebrates increased along the treatment process. Problems associated with excessive propagation and leakage of invertebrates in drinking water have received increasing attention in recent years. We performed a monthly survey of invertebrate abundance and taxa in the effluent of each treatment stage in a drinking water treatment plant between May 2015 and April 2016 and analyzed seasonal and treatment-process variations in invertebrates. The results showed that invertebrate abundances in raw water, effluent of the biological activated carbon (BAC) filter, and finished water significantly correlated with water temperature, whereas no correlation was observed between water temperature and invertebrate abundance in the effluents of the sedimentation tank and sand filter. The dominant taxa in the effluent of each treatment stage were rotifers, nematodes, and crustaceans. The sedimentation tank could efficiently remove invertebrates with an annual average removal rate of 92%. The propagation and leakage of invertebrates occurred in the sand and BAC filters but more seriously in the latter. The average reproduction rate in the BAC filter was 268.8% with rotifers as the taxon that leaked the most. Invertebrate survival and reproduction were also observed in the chlorine-disinfected clean water reservoir with an average reproduction rate of 41.9%. Owing to differences in chlorine resistance, the reproduction ability of the dominant taxa was in the order nematodes>crustaceans>rotifers. The proportion of endogenous invertebrates gradually increased along the treatment process. The average proportion of endogenous invertebrates in the finished water was higher than 79.0%. Our findings suggested that waterworks should pay more attention to endogenous invertebrate growth.

关键词： Invertebrates     Drinking water     Seasonal variations     Treatment process    

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Bioaerosol emissions variations in large-scale landfill region and their health risk impacts

《环境科学与工程前沿（英文）》 2022年 第16卷 第12期 doi: 10.1007/s11783-022-1593-9

摘要：

● The airborne bacteria in landfills were 4–50 times higher than fungi.

关键词： Microbial aerosols     Landfill sites     Health risk assessment     CALPUFF    

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标题 作者 时间 类型 操作

Applicability of the Arrhenius model for Ammonia Oxidizing Bacteria subjected to temperature time gradients

Alberto MANNUCCI,Giulio MUNZ,Gualtiero MORI,Claudio LUBELLO,Jan A. OLESZKIEWICZ

期刊论文

Phase separation time/temperature dependence of thermoplastics-modified thermosetting systems

ZHANG Xiujuan, XU Yuanze, YI Xiaosu

期刊论文

Field test on temperature field and thermal stress for prestressed concrete box-girder bridge

Baoguo CHEN, Rui DING, Junjie ZHENG, Shibiao ZHANG

期刊论文

Real-time tool condition monitoring method based on temperature measurement and artificial neural network

期刊论文

Development of realistic design fire time-temperature curves for the testing of cold-formed steel wall

Anthony Deloge ARIYANAYAGAM,Mahen MAHENDRAN

期刊论文

Evaluating the short-term effect of ambient temperature on non-fatal outdoor falls and road traffic injuriesamong children and adolescents in China: a time-stratified case-crossover study

期刊论文

New technique of precision necking for long tubes with variable wall thickness

Yongqiang GUO, Chunguo XU, Jingtao HAN, Zhengyu WANG

期刊论文

Supercritical carbon dioxide extraction of CLA-ethyl ester

Yingdi CHEN, Peng XU, Jian CHENG

期刊论文

Achieving High Strength and Tensile Ductility in Pure Nickel by Cryorolling with Subsequent Low-TemperatureShort-Time Annealing

Zhide Li,Hao Gu,Kaiguang Luo,Charlie Kong,Hailiang Yu,

期刊论文

Effects of sulfur on variations in the chemical speciation of heavy metals from fly ash glass

期刊论文

Genomic variations in the counterpart normal controls of lung squamous cell carcinomas

null

期刊论文

prediction and optimization design of sustainable concrete based on squirrel search algorithm-extreme gradient

期刊论文

Time- and temperature-dependence of compressive and tensile behaviors of polypropylene fiber-reinforced

期刊论文

Seasonal and treatment-process variations in invertebrates in drinking water treatment plants

Zhiling Wu, Xianchun Tang, Hongbin Chen

期刊论文

Bioaerosol emissions variations in large-scale landfill region and their health risk impacts

期刊论文